Steel and Aluminium Moulds: Comparative Analysis of Optimal Parameters to Inject Amorphous and Semicrystalline Polymers

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Steel and Aluminium Moulds: Comparative Analysis of Optimal Parameters to Inject Amorphous and Semicrystalline Polymers

Author Information
1
Graduate Program in Mechatronics, Federal University of Bahia, Salvador 40210-630, Brazil
2
Graduate Program of Industria Engineering, Federal University of Bahia, Salvador 40210-630, Brazil
3
Graduate Program in Mechanical Sciences, Federal University of Santa Catarina, Joinville 89219-600, Brazil
4
Department of Industrial Product Development, Senai Cimatec, Av. Orlando Gomes, 1845-Piatã, Salvador 41650-010, Brazil
*
Authors to whom correspondence should be addressed.
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Advanced Materials & Sustainable Manufacturing 2025, 2 (2), 10006;  https://doi.org/10.70322/amsm.2025.10006

Received: 17 January 2025 Accepted: 07 April 2025 Published: 27 April 2025

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© 2025 The authors. This is an open access article under the Creative Commons Attribution 4.0 International License (https://creativecommons.org/licenses/by/4.0/).

ABSTRACT: The thermoplastic injection moulding process is very important in the plastics industry, as it enables automated production, supports high productivity and allows the production of plastic parts with complex geometries. It is possible to split into two large groups of polymers: amorphous and semicrystalline. Cooling rate and other injection moulding parameters have a great influence on the final properties of the plastic part. Regarding the use of aluminium as cavity material in injection moulds, new variables must be included in the analysis, since its thermal properties are significantly different from those presented by steels, which are traditionally used. In this way, the purpose of this study was to evaluate the effect of aluminium and steel cavities on different types of thermoplastics belonging to the two classes of polymers by assessing the injection parameters of a high-production part (automotive cup holder). In terms of productivity factors, moulds made of aluminium using semicrystalline polymers showed more significant reductions in cycle time compared to amorphous materials. Specifically, polypropylene exhibited a cycle time reduction between 40.6% and 52.5% when compared to steel moulds, while polyamide showed an even more substantial reduction, ranging between 56% and 63.5%. As for warpage, the amorphous materials displayed the lowest values for both types of moulds, but they also exhibited greater variations in isothermal simulations compared to semicrystalline materials. In relation to the mould materials, aluminium mould exhibited the lowest warping results and smaller variations compared to the isothermal analyses for all polymers.
Keywords: Thermoplastic injection mould; Amorphous; Semicrystalline; Taguchi method; Numerical simulations; Injection moulding

1. Introduction

The thermoplastic injection moulding process has great industrial relevance since it allows for the high production of plastic parts with complex geometries. However, to obtain parts with the desired quality and competitive characteristics in the market, it is necessary to understand and control the process parameters. In general, these parameters range from the choice of polymer to the characteristics of the selected mould. In addition to the economic factor, the proper choice of polymer is essential to ensure the quality and performance of the final part since the mechanical, thermal and processing properties directly influence the efficiency of the process and the characteristics of the injected part. Thermoplastics are divided into two main classes: amorphous and semicrystalline polymers. Both classes have particularities, mainly regarding the behaviour of molecular reorganization during the cooling phase, as can be seen in Figure 1. These aspects directly affect the degree of crystallinity of the polymers, thus directly influencing the dimensional quality of the produced part. Additionally, the rate at which the polymer in the molten state cools also directly affects the formation of crystalline regions. Slow cooling allows more time for polymer chains to organize into crystalline structures, which may result in a higher degree of crystallinity. The presence of additives or fillers in the polymer matrix can also affect nucleation, facilitating the formation of crystalline regions. The degree of crystallinity can vary with the processing conditions and with the thermal history of the polymer: it is not a fixed property; thus, all these factors must be evaluated to define the adequate injection process.
Figure 1. Microstructure of semicrystalline and amorphous polymers during processing. Adapted from Shoemaker [1].
In the context of physical phenomena related to thermoplastic material during the injection process, it is important to note that volumetric contraction is an inherent property of polymer crystallization. If an excessive and non-uniform contraction occurs, either in general scope or in specific cross-sections of the part, this can result in unwanted deformations in the manufactured plastic part [1]. Kazmer [2] points out that semicrystalline polymers have high contraction rates during cooling when compared to amorphous materials. For this reason, the shrinkage rate of semicrystalline polymers is highly dependent on the cooling fluid temperature and cooling rate. In Figure 2, Shoemaker [1] presents the behaviour of the specific volume of amorphous and semicrystalline materials as a function of pressure and temperature.
Figure 2. PVT diagrams for polymers. Adapted from Shoemaker [1].
When analyzing the graphs in Figure 2, it is possible to observe that semicrystalline polymers exhibit a “step-like” specific volume variation on cooling, mainly at the melting temperature. Semicrystalline polymers show an increase in specific volume with increasing temperature (at constant pressure) due to thermal expansion. They also show a decrease in specific volume with increasing pressure (at constant temperature) due to compressibility effects. In this perspective, Malloy [3] mentions that, as the semicrystalline polymer presents amorphous and crystalline regions, during the cooling process, the “molten amorphous portion” cools and solidifies as it reaches its crystallization temperature. The significant decrease in volume associated with the phase change occurs as the polymer molecules pack into ordered crystalline regions, as seen in Figure 1. In addition to the choice of polymer, the mould material must also be taken into consideration, since the thermal properties will directly affect productivity (cycle time) and quality of the injected part. Historically, the thermoplastic injection process aimed at high production uses moulds made of steel based on its excellent mechanical properties (such as its high mechanical strength) and the extensive technical and scientific experience available regarding its use. Despite its several advantages, steel has a relatively low thermal conductivity compared to other materials, such as aluminium alloys, which display up to five times greater conductivity. The high thermal conductivity provides moulds made of aluminium with better heat distribution and dissipation, when compared to those observed when using steel moulds, reducing production cycle times by 20 to 80% [4,5,6,7,8]. Nonetheless, as noted by Arieta Filho [9], although aluminium exhibits superior thermal properties, it is more susceptible to mechanical wear than steel because of its lower mechanical strength. Numerous studies have investigated the use of aluminium alloys in mould injection, particularly in prototyping. The thermomechanical properties of these alloys emphasize that aluminium is an excellent option for manufacturing prototype moulds [10,11,12,13,14,15]. In terms of mass production, aluminium alloys are more widely accepted in processes such as reaction injection moulding (RIM) [16] and resin transfer moulding (RTM) [17], as these require less mechanical effort than conventional injection moulding. However, Arieta et al. [18] highlighted that leading automakers like GM, Nissan, and Tesla had adopted aluminium moulds for high-volume production. In this context, Pereira et al. [19] carried out a study regarding the use of steel and aluminium moulds and verified the presence of hot spots in the steel mould, which was a decisive factor in increasing the cooling time of the part by 22.86 s in addition to the time required for demoulding the part. This did not happen with the aluminium moulds, leading to a shorter cooling time. Thus, considering the time of 3 s for opening and 2 s for closing the mould, the total injection cycle time for the steel mould was 43.75 s, and for the aluminium mould was 23 s, which corresponds to a 47.43% reduction in the total cycle time. Marconi et al. [5] explored the relationship between the material used for mould production (steel or aluminium) and the thickness of the injected part, examining how these factors impact the efficiency of the process in terms of the quantity and quality of the produced parts. The findings suggest that substituting steel moulds with aluminium alloys can significantly shorten the injection moulding cycle, with reductions ranging from 57.1% to 72.5%. Despite the extensive research on the application of aluminium moulds, there is limited literature on how the thermal properties of this material impact injection moulding, resulting in uncertainties regarding the optimal injection parameter ranges. Additionally, there are no specific references concerning its use in the production of parts from different classes of polymers, necessitating an investigation into the feasibility of this alloy for manufacturing both amorphous and semicrystalline components. Insights into how these materials behave under different processing conditions could potentially promote the use of aluminium tooling in specialized high-volume injection moulding applications. In view of the above, the present study aims to evaluate the differences found in the injection parameters of a plastic part, simulated in steel and aluminium moulds, using amorphous and semicrystalline polymers. Thus, this work is divided into three sections: the first one consists of an approach to the methodology regarding the conduction of the rheological simulations, as well as the presentation of the mould’s materials and the polymers; the second one presents the results of simulations and statistical analyses; and the third one presents the conclusions of this work.

2. Materials and Methods

The Taguchi experimental planning is a fractioned factorial experimental planning method, which consists of executing only a fraction of the total number of combinations of the input variables. Moita [20] states that Taguchi himself classified this method as an “offline quality control”, because its application involves a small number of samples from trial phases, which present high variance levels in terms of quality parameters in comparison with production parts (“online quality control”). Rosa et al. [21] point out that the Taguchi method allows for the determination of the optimum combination of factors and interactions that influence the variable-response behaviour from a given process, requiring fewer samples and decreasing testing costs without affecting the conclusions. Given that a Design of Experiments (DOE) performs the experiments in many cases, it is necessary to make use of statistical tools for a better understanding and interpretation of the results. For that purpose, the ANOVA is suitable since it allows for the identification of the most important parameters for a certain response variable. In this context, Montgomery e Runger [22] highlight that the ANOVA is a statistical method that assists data interpretation and decision making, and to statistically test results in different conditions. The statistical variables used to assess the results are the R2, the P-Value and the intrinsic error of the model. In this work, statistical methods are applied to the numerical simulations’ results for the identification of the processing parameters of different polymers (amorphous and semicrystalline) to assess the performance of different mould materials (steel and aluminium). This work aims to evaluate the feasibility of mould injecting such polymers in those mould’s materials, in terms of production time and quality of the moulded part. The numerical simulations were performed with the software MoldFlow 2024TM, while the statistical tests were carried out with the statistics software Minitab 19TM. 2.1. Polymers and Mould Materials The amorphous polymers considered in this work were the Acrylonitrile Butadiene Styrene (ABS) and the Polycarbonate (PC). Regarding the semicrystalline polymers, this work considered Polypropylene (PP) and Polyamide (PA). These thermoplastics are widely used in injection moulding processes. Furthermore, it is worth highlighting that the materials’ selection considered the differences related to their mechanical and physical properties, e.g., the elastic modulus, the Poisson’s ratio, and the density. The processing ranges of the materials were also considered, particularly the molten and mould temperature. All the polymers selected comply with the golden quality indicators, which means that their injection moulding data were obtained in laboratory environments and approved by Autodesk, the company that owns MoldFlowTM. The information about the polymers is shown in Table 1. The processing parameters are shown in Table 2.

Table 1. Polymers properties obtained through MoldFlowTM.

Polymer Manufacturer Commercial Name Elastic Modulus (MPa) Poisson’s Ratio Density (kg/m3)
Acrylonitrile butadiene styrene (ABS) Kingfa Sci & Tech Co., Ltd. Qingyuan (China) HR-527A 2308–2326 0.37–0.38 1045
Polyamide (PA) Kuraray
Tokyo (Japan)
Genestar R480G 3737–4228 0.36–0.37 1561
Polycarbonate (PC) Covestro
Leverkusen (Germany)
Makrolon 2807 2283–2307 0.39 1202
Polypropylene (PP) Kingfa Sci & Tech Co., Ltd.
Qingyuan (China)
ABP-2036 GT 1908–2139 0.314 1045

The recommended operating range for mould and melt temperature for each polymer according to the MoldflowTM library is shown in Table 2.

Table 2. Recommended operating range obtained through MoldFlowTM.

Polymer Mould Temperature (°C) Melt Temperature (°C)
ABS 40–80 210–260
PA 140–160 330–350
PC 80–120 280–320
PP 20–50 190–245

To perform the numerical simulations, AISI P20 steel was used for the steel mould, due to its wide use in the injection process. Regarding the aluminium alloy, the 7075-T651 alloy was used due to its high mechanical strength, which allows it to be used in high-production processes. Table 3 shows the mechanical and thermal properties of the mould materials used.

Table 3. Mechanical and thermal properties of mould materials.

Properties AISI P20 Aluminium 7075-T651
Density (kg/m3) 7800 2795.6
Thermal Conductivity (W·m−1·K−1) 29 137
Coefficient of thermal elasticity (K−1) 1.2 × 10−5 2.35 × 10−5
Elastic modulus (GPa) 205 70
Heat capacity (J·kg−1·K−1) 460 931.5
Poisson’s ratio 0.29 0.34

The geometry chosen as a case study for the development of the present work was an automotive cup holder with a nominal thickness of 2 mm, which includes geometric complexity and high productivity, as can be seen in Figure 3.
Figure 3. CAD views of injection moulded par (cup holder).
2.2. Cooling Systems for Steel and Aluminium Moulds Based on the recommendations proposed by Kazmer [2] and considering that the thermal conductivity of aluminium is higher steel’s, the cooling systems of these moulds have geometrical differences in relation to the distances between the channels and in relation to the surface of the mould cavity. Thus, the designed cooling systems considered the use of 26 and 14 baffles for the steel and aluminium moulds, respectively. For the baffle diameter values, 16 mm was adopted on the fixed mould plate (cavity) and 14 mm for those positioned on the movable plate (core). Figure 4 shows the differences found in the configuration of the cooling systems for the steel and aluminium mould.
Figure 4. Mould cooling system: (<b>a</b>) steel and (<b>b</b>) aluminium.
2.3. Experimental Planning (FPW and Cooling) Initially, experimental plans were carried out only considering isothermal analysis to define the ideal processing conditions for the filling and compacting phases to maximize the dimensional quality of the part. These simulations consider as a boundary condition that the surface of the mould is maintained at a constant temperature, which allows idealizing the cooling system for the condition of the best possible temperature distribution. Thus, four experimental plans were carried out containing a total of 74 combinations (for each polymer) referring to the FPW module of MoldFlowTM, totalling 296 rheological simulations related to this module. Each planning included six injection parameters: mould temperature, melt temperature, injection time, percentage of filled volume for switching control, packing time and packing pressure (as a function of the maximum injection pressure). The factors were divided into different levels, with 3 levels for mould temperature, melt temperature and percentage of filled volume for switching control; and 4 levels for injection time, packing time and packing pressure. Table 4 shows the levels used for each injection parameter in relation to the polymers used in the simulations.

Table 4. Injection levels and parameters of the experimental planning (FPW).

Polymer Melt Temperature (ºC) Mold Temperature (ºC) Injection Time (s) By % Volume Filled Packing Time (s) Packing Pressure (%)
ABS 210–235–260 40–60–80 1–2–3–4 97–98–100 2–4–7–10 60–70–80–90
PA 330–340–350 140–150–160 1–2–3–4 97–98–100 2–4–7–10 60–70–80–90
PC 280–300–320 80–100–120 1–2–3–4 97–98–100 2–4–7–10 60–70–80–90
PP 190–217–245 20–35–50 1–2–3–4 97–98–100 2–4–7–10 60–70–80–90

In order to determine which parameters in Table 4 have the greatest influence on warpage results, four analyses of variance (ANOVA) were conducted using data from FPW simulations for each type of polymer. The purpose is to evaluate whether the use of different polymers significantly affects the results of the statistical test. Based on the process parameters obtained in the previous analysis, the methodology proposed by Soares et al. [23] was used for the optimization of process parameters related to the cooling step. These authors suggest combining the geometric configuration of the cooling system, established on literature recommendations, with the other parameters defined in the cooling analysis step, so that certain quality factors are achieved. These factors are related to the temperature uniformity of the mould cavity and cooling system efficiency. Thus, if the proposed cooling system (Figure 4) meets the recommendations in the literature, the next step consists of carrying out new experimental planning, contemplating combinations that allow the variation of temperature, pressure or flow of the cooling fluid. The objective of this second stage is to reach the optimal values related to mould cooling, so that it can achieve the best possible heat distribution (uniformity) associated with the shortest cooling time, maximizing process productivity and part quality. From the procedure reported above, four experimental plans were carried out (one for each polymer), totalizing 16 combinations. Each planning considers two factors: temperature and pressure of the coolant, which were divided into 4 different levels, varying the intervals from the values obtained in the injection parameters. To determine the temperature range of the coolant, the mould temperature determined in the isothermal analysis is the main parameter. Regarding the pressure, the values varied from the turbulence conditions acceptable to the process (turbulent regime) and operating conditions of the injection machine. In addition, as they are materials from different moulds, the same experimental planning was chosen for a better comparison of the results found in the cooling step.

3. Results

To better present the results found in this work, this section was divided into three subsections. The first one presents the configuration of the parameters that minimized the warpage, considering the isothermal analyses, as well as the ANOVA in relation to each polymer. The second shows the results related to the cooling step, regarding the cooling time and the convergence of each polymer in relation to the permanent regime of the injection process. Finally, the third one presents the results related to the warpage of the part. 3.1. Filling and Packing Results The configurations that minimized the warpage of the part were obtained through the DOE created from the six injection parameters (Table 4). Considering the nature of the polymers (amorphous and semicrystalline), as well as their properties, each material presented an ideal configuration, as can be seen in Table 5.

Table 5. Optimal configuration of the Filling and Packing parameters of the MoldFlowTM module.

Polymer Melt Temperature (ºC) Mould Temperature (ºC) Injection Time (s) By % Volume Filled Packing Time (s) Packing Pressure (%) Packing Pressure (MPa)
ABS 210 40 4 97 2 90 137.3
PA 350 150 1 97 2 90 4.7
PC 280 100 1 97 7 90 92.3
PP 245 50 4 100 10 80 16.3

From the analysis of the results presented in Table 5, it was possible to observe a difference in the FPW parameters for the polymers used. Regarding the injection parameters, the values referring to the packing pressure stand out: the amorphous polymers presented higher pressures compared to semicrystalline polymers. According to Rosato et al. [24] (2000), amorphous polymers gradually soften as they are heated, but do not flow as easily during moulding as semicrystalline materials, requiring higher injection pressures. It is important to highlight that high pressures may be an impediment to the use of moulds made of aluminium, since these materials have lower mechanical strength when compared to steel [25,26,27]. An ANOVA was performed based on a first-order polynomial regression model for each polymer with the warpage results from the MoldFlowTM FPW module simulations (as shown in Table 4). The intention was to verify which of the parameters used had the most influence on the results. The criterion adopted to verify the quality of the fit of the models to the data was the R2 value (regression) and p-value for the parameters. The developed models follow the character described in Equation (1)
```latexw = k + m_{e} t + m_{o} t + i t + v f + p t + p p```
where $$w ,$$ $$m_{e} t , m_{o} t , i t , v f , p t , p p$$ represent, respectively, the variables warpage, melt temperature, mould temperature, injection time, by % volume filled, packing time, packing pressure; and k represents the value of the constant that best fitted the model. Table 6 shows the results related to ANOVA for each model developed for each polymer, as well as the contribution of each parameter regarding the prediction of part warpage.

Table 6. ANOVA data for the warpage prediction models for each polymer obtained through MinitabTM.

Model Parameters Semicrystalline Polymers Amorphous Polymers
PP PA ABS PC
Source Contribution p-value Contribution p-value Contribution p-value Contribution p-value
Regression 79.44% 0.00000 87.31% 0.000 93.69% 0.000 89.63% 0.00000
$$m_{e} t$$ 56.25% 0.00000 34.90% 0.000 57.42% 0.000 43.14% 0.00000
$$m_{o} t$$ 0.07% 0.04735 0.87% 0.064 5.13% 0.000 16.92% 0.00000
$$i t$$ 6.36% 0.00000 45.88% 0.000 13.52% 0.000 6.02% 0.00000
$$v f$$ 8.62% 0.00000 1.51% 0.000 2.15% 0.000 0.72% 0.00000
$$p t$$ 2.03% 0.00004 1.45% 0.007 3.84% 0.000 8.33% 0.00000
$$p p$$ 6.11% 0.00000 2.69% 0.000 11.63% 0.000 14.51% 0.00000
Error 20.56% 12.69% 6.31% 10.37%
Lack-of-Fit 20.56% 12.69% 6.31% 10.37%
Pure Error 0.00% 0.00% 0.00% 0.00%
Total 100.00% 100.00% 100.00% 100.00%

Based on the results from Table 6, it was possible to observe that the melt temperature is the most significant parameter regarding the warpage, except for the PA, for which the injection time showed a greater contribution. This influence is related to the high thermal conductivity of polyamide, which allowed the extraction times to be 3–4 times shorter compared to the other polymers evaluated. Thus, as the time interval is reduced for the crystallization process of the material to occur, the injection time ends up having a greater influence on warpage. It is worth mentioning that the evaluations regarding the FPW simulations do not depend on the type of the mould material, since the temperature of the mould cavity is kept constant during the whole process. 3.2. Cooling Results Four experimental plans were carried out, varying the cooling fluid processing parameters and based on the injection parameters obtained in the isothermal analyses (Table 5). The temperature and pressure of the cooling fluid were varied in four levels, generating a plan with 16 combinations. It is worth mentioning that water was used as a cooling fluid for the PP, PC and ABS polymers, differing from the PA polymer, for which oil was used. The difference in the cooling fluid was due to the high mould temperature (150 °C) obtained in the isothermal analyses. In addition, a different pressure variation was used for oil compared to water due to the higher viscosity presented by the former, thus ensuring turbulence in the process. Table 7 shows the data for the experimental designs of the cooling of each polymer.

Table 7. Taguchi experimental planning of cooling obtained through MinitabTM.

Polymer Coolant Coolant Temperature (ºC) Coolant Pressure (bar)
ABS Water 20–25–30–35 0.5–1.0–1.5–2.0
PA Oil 130–135–140–145 2.0–4.0–6.0–8.0
PC Water 80–85–90–95 0.5–1.0–1.5–2.0
PP Water 30–35–40–45 0.5–1.0–1.5–2.0

Evaluating the quality criteria related to the cooling system proposed by Soares et al. [23], the processing parameters approved in the methodology for each material are presented in Table 8. The results obtained that met the quality criteria used the hot cooling fluid (above room temperature). According to Jeng et al. [28], with a high mould surface temperature, the surface quality of the part will be better, although the cooling time and, consequently, the cycle time will increase.

Table 8. Approved cooling processing conditions.

Polymer Approved Cooling Processing Conditions
Coolant Temperature (ºC) Coolant Pressure (bar)
Steel Aluminium Steel Aluminium
ABS 30–35 0.5–1.0–1.5–2.0
PA 140–145 2.0–4.0–6.0–8.0
PC 90–95 0.5–1.0–1.5–2.0
PP 40–45 0.5–1.0–1.5–2.0

Table 9 shows the results obtained from the approved processing conditions. For each polymer, cooling intervals were determined for the steel and aluminium mould, based on the quality criteria defined by Soares et al. [23]. The table displays two important results: one for the cooling time intervals and another for the total cycle time for each mould material. It is important to highlight that there were hotspots in the steel mould cavity for all polymers, requiring an increase in cooling time to meet the quality criteria. Regarding the aluminium mould, only the mould that operated with polyamide (PA) presented hotspots, which also required additional time to uniform the cavity surface.

Table 9. Results of the approved processing conditions.

Polymer Cooling Time (s) Cycle Time (s)
Steel Aluminium Steel Aluminium
ABS 13–20 6–7 24–31 17–18
PA 42–44 11–14 50–52 19–22
PC 13–19 6–7 26–32 19–20
PP 13–21 0 32–40 19

Although amorphous polymers require longer periods to reach the extraction temperature than semicrystalline polymers, due to their disordered molecular structure, they showed lower cycle times when using steel moulds. This is because the injection parameters obtained in the FPW analyses concerning the times (injection and packing) were smaller. For moulds made of aluminium, semicrystalline polymers showed more significant reductions in cycle time compared to amorphous materials. Polypropylene showed a cycle time reduction between 40.6 and 52.5% compared to steel moulds, while polyamide showed a reduction between 56 and 63.5%. According to Rosato et al. [24], the high degree of molecular order of semicrystalline polymers tends to make their thermal conductivity values twice as high as those of amorphous plastics. Furthermore, the high heat dissipation and uniformity in the aluminium mould are high, the polypropylene did not require additional cooling time to achieve the quality factors. Although polyamide obtained the lowest values for extraction time among all the polymers evaluated, the cooling time required to achieve the quality criteria of uniformity in the cavity was the highest. This is due to the high temperature of the mould and the use of oil as a cooling fluid, which has inferior heat transfer properties compared to water. Unlike the cycle time results presented in Table 9, the time for convergence in relation to the permanent regime showed discrepancies both in relation to the mould materials and in relation to the polymers. To carry out the evaluation, the stopping criteria used for the transient cooling simulations were defined from the following values: when achieving a total of 100 operating cycles or a maximum mould temperature variation of 0.5 °C between cycles. Figure 5 shows the graphs showing the behaviour of the processes from the start of injection.
Figure 5. Transient profile of the injection process until reaching the permanent regime obtained through MoldFlow<sup>TM</sup>.
From the results in Figure 5, it is possible to see that the aluminium mould tends to converge to the steady state faster when compared to the steel mould. This behaviour occurs because the first has a significantly higher thermal conductivity than the former, so the heat is transferred faster through the aluminium during mould cooling, leading to faster convergence to the steady state. According to Rosato et al. [24], simulation software that uses transient analysis to assess the steady state of the mould and the part also takes into account the variation in the specific heat and thermal conductivity of the polymer during cooling, which justifies the discrepancy in relation to the time to reach the permanent regime of each material. Overall, the number of cycles required to reach the steady state behaviour was linked to the temperatures of the moulds. Thus, moulds that use higher temperatures need more time to reach a steady state. The same processing conditions for each evaluated polymer (temperature and pressure of the cooling fluid) were used to evaluate the results in all four cases. In addition, to evaluate the behaviour of the graphs, the same node as the mould surface was used, ensuring sensitivity to the behaviour of the data. 3.3. Warpage Results The results in Table 10 show the outcomes obtained through the experimental planning using the FPW modules (isothermal simulations) exclusively, considering the approved combinations listed in Table 5.

Table 10. Warpage results from FPW analyses (isothermal).

Polymer FPW Warpage (mm)
ABS 0.401
PA 3.506
PC 0.566
PP 0.676

The maximum warpage ranges were determined for each polymer type and mould material after performing the full cycle analysis of the approved processing conditions in the cooling step (as shown in Table 8). Table 11 shows the warpage results, considering the transient analysis.

Table 11. Warpage results of the complete cycle.

Polymer Maximum Warpage (mm) Variations from the Warpage of the Isothermal and Transient Simulations (Ref.) (%)
Steel Aluminium Steel Aluminium
ABS 0.52–0.57 0.44–0.51 29.7–42.1 9.7–27.2
PA 3.48–3.50 3.49–3.50 0.2 &#42;–0.7 &#42; 0.2 &#42;–0.5 &#42;
PC 0.65–0.69 0.55–0.58 14.8–21.9 2.5–2.8 &#42;
PP 0.72–0.80 0.68–0.73 6.5–18.3 0.6–8.0

* Reduction in relation to warpage considering isothermal simulation.

The results in Table 11 show the maximum warpage for steel and aluminium moulds for each material. In general, the aluminium mould presented smaller warpages than the steel mould, and therefore presented smaller variations in relation to the isothermal simulations. These results are justified by the fact that the high conductivity of aluminium allows rapid heat dissipation and consequently, greater cavity uniformity, reducing deformations inherent to differential cooling. The amorphous materials showed the lowest values for both moulds, and the greatest variations in isothermal simulations compared to semicrystalline materials, which indicates that the cooling system had a greater influence on the dimensional quality of these materials. This discrepancy is due to molecular reorganization during the cooling phase. However, the warpage of these materials is small; for the most acute case, the variation corresponds to 42.1%, which is equivalent to 0.12 mm. Thus, despite having greater variations, they do not compromise the dimensional quality of the part. In general, the reduced variations in isothermal simulations indicate that the warpage is more related to the injection processes than the cooling parameters.

4. Conclusions

To optimize the processing parameters for different classes of polymers, this study was developed based on the evaluation of the main injection and cooling parameters, aiming at the productivity and dimensional quality of parts produced in steel and aluminium moulds. When evaluating the results in general, aluminium moulds show a significant reduction in relation to the total cycle time, one that ranges from 25 to 63.5% for all polymers. It is important to mention that, in relation to the mould materials, the aluminium mould exhibited the lowest warping results and smaller variations compared to the isothermal analyses for all polymers. This outcome indicates that its thermal properties enable efficient dissipation and uniformity of the mould surface, leading to better control during polymer cooling and reducing warping caused by differential cooling. For amorphous polymers, the results indicated that higher pressures were required to fill the cavity completely. Therefore, due to their lower rigidity and high thermal conductivity, aluminium moulds are not recommended for this type of polymer in high-volume production processes. Conversely, semicrystalline polymers required lower pressures, and aluminium moulds provided better dimensional quality than steel moulds. This result suggests that these tools could be a viable alternative for manufacturing large volumes of parts using aluminium moulds. In this scenario, the use of numerical simulations associated with experimental planning to verify the processing parameters of different polymers proved to be a very useful tool, as it allows the evaluation of nuances, both in relation to the quality of the part and in relation to the structural integrity of the moulds. These nuances associated with project requirements, such as mechanical properties, dimensional quality, among others, provide fundamental information to designers during the evaluation of the use of amorphous and semicrystalline materials in steel and aluminium moulds.

Acknowledgments

This work is a partial result of the DEMALAP Project—Aluminium Mould Demonstrator for High Production sponsored by the Rota 2030 Program of the Federal Government described in Law No. 13,755/2018 and is coordinated by FUNDEP. The executors of the project are the universities SENAI CIMATEC, UFBA and UFSC. We are grateful to the other project partners for their support: ESSS Engineering Simulation and Scientific Software Ltd.a, Ford Motor Company Brasil Ltd.a; Moldit Brasil Ltd.a, Open Mind Tecnologia Brasil Ltd.a, Renault do Brasil S.A, SMRC Fabricação e Comércio de Produtos Automotivos do Brasil Ltd.a and Union Indústria de Moldes e Comércio Atacadista de Máquinas Eireli.

Author Contributions

Conceptualization, P.G.C.S.M., E.M.S.A. and A.S.R.J.; Methodology, P.G.C.S.M. and A.S.R.J.; Software, P.G.C.S.M.; Investigation, P.G.C.S.M. and E.M.S.A.; Writing—Original Draft Preparation, P.G.C.S.M. and E.M.S.A.; Writing—Review & Editing, R.L.L.F., C.V.F., V.E.B. and A.S.R.J.; Supervision, A.S.R.J.

Ethics Statement

Not Applicable.

Informed Consent Statement

Not Applicable.

Data Availability Statement

The data supporting the conclusions of this study are available from the corresponding author upon reasonable request.

Funding

This work is involved in a project sponsored by the Brazilian Federal Government’s Rota 2030 Program described in Law No. 13.755/2018 and is coordinated by FUNDEP.

Declaration of Competing Interest

The authors declare that they have no known competing financial interests or personal relationships that could have appeared to influence the work reported in this paper.

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