Deadline for manuscript submissions: 28 February 2025.
Lithium batteries pave way for rapidly reducing greenhouse gas emissions. Still there are concerns associated with battery sustainability, such as the supply of key battery materials like cobalt, nickel and carbon emissions related to their manufacture. While LiMn2O4 spinel is a common cathode material for Li-ion batteries that remove Co and Ni, studies on over-stoichiometric variants and their behavior across a broad potential range may be limited. Research in this area could provide valuable insights into the performance, stability and electrochemical characteristics of such cathodes, offering potential benefits for the development and optimization of Li-ion battery technologies. This study investigates the electrochemical behavior of Li-rich Li1+yMn2−yO4−δ (LMO, y ≈ 0.03, δ ≈ 0.01) spinel as a cathode in Li-ion batteries, focusing on the phenomenon of extra capacity under the extended operating voltage 1.5–4.8 V vs. Li+/Li. The nanostructured LMO sample synthesized by sol-gel method and calcined at 900 °C is characterized by X-ray diffraction, scanning and transmission electron microscopy and surface area measurements. The Li-rich spinel electrode delivers a specific discharge capacity of 172 mAh g−1 at 1st cycle. It retains 123 mAh g−1 at the 100th cycle (71.5% capacity retention) at current density of 100 mA g−1 current density (i.e., ~0.7 C rate). An excellent stability is obtained in the 1.5–4.8 V potential window, with a discharge capacity of 77 mAh g−1 after 500 cycles at the same current density, owing to the reduction of the Jahn-Teller effect by Li doping. These results contrast with the specific capacity of 85 mAh g−1 (1st cycle) and the capacity retention of 54.3% after 100 cycles, obtained when the cell operates in the narrow potential range of 3.0–4.5 V.
In the mechanical cutting process, the surface defects of the workpiece are an important indicator of cutting quality and also reflect the condition of both the machine tool and the cutting tool. Effective detection of defects on the surface of the workpiece plays an important role in adjusting the processing conditions promptly, reducing losses, improving the utilization rate of the workpiece, and maintaining the normal operation of the equipment. To address the challenge of detecting surface defects on workpieces, an inspection method based on an improved Single Shot Multibox Detector (SSD) model is proposed. The method simplifies the detection model and reduces the computation by proposing a DH-MobileNet network instead of a VGG16 network in the SSD structure. The inverse residual structure is also used for position prediction, and null convolution is used instead of a down-sampling operation to avoid information loss. A scanning electron microscope was used to obtain the surface image of the workpiece. A dataset of workpiece surface defects was constructed and expanded, then used to train and test the model for detecting three common types of high-frequency defects: peel-off, chip adhesion, and scratches. The effect was compared with YOLO, Faster R-CNN, and the original SSD model. The detection results show that the method can detect the defects on the surface of the workpiece more accurately and quickly, which provides a new idea for defect detection in real industrial scenarios.