Issue 1, Volume 3 – 4 articles

Review

30 December 2024

Fire-Retardant Wastepaper Reinforced Waste Polyethylene Composite: A Review

The increase in fire outbreaks recently and the need for eco-friendly and fire-resistant materials have inspired a wave of studies, focusing on producing innovative composite materials with effective fire-resistant properties. This review delves into the world of fire-resistant wastepaper-reinforced waste polyethylene composites. Using wastepaper as a strengthening factor in polyethylene matrices, combined with fire-retardant additives like nanoparticles, introduces a hopeful path for waste management and improved material properties. This work carefully considers the combining approaches, physical and mechanical properties, fire-resistant mechanisms, and environmental impacts of these composites. The review underscores the possible and potential applications, difficulties, and prospects of such environmentally friendly materials in various industries. Understanding these composites’ blending, attributes, and conceivable utilization is essential for advancing maintainable and fire-safe material innovation in pursuing a greener future.

Communication

08 January 2025

Development of Eco-Friendly Composites Using Poly(3-hydroxybutyrate-co-3-hydroxyvalerate) and Diss Fibers (Ampelodesmos Mauritanicus)

In response to the growing environmental threats and pollution linked to synthetic plastics, current scientific inquiry is prioritizing the advancement of biodegradable materials. In this context, this study investigates the possibility of developing fully biodegradable materials using plant fibers extracted from the Diss plant (Ampelodesmos mauritanicus) as reinforcement in poly(3-hydroxybutyrate-co-3-hydroxyvalerate) (PHBV)-based biocomposites. The biocomposites were prepared by melt blending in the following weight ratio: PHBV/Diss fibers 80/20. The chemical structure of Diss fibers was characterized by Fourier transform infrared spectroscopy (FTIR) and X-ray fluorescence spectrometry (XRF). The impact of Diss fibers on the mechanical properties of biocomposites has also been investigated in comparison to neat PHBV. FTIR and XRF analyses identified cellulose, hemicellulose, and lignin as the main components of Diss fibers. On the other hand, the results showed a significant enhancement of Young’s modulus (⁓21%) of PHBV/DF biocomposites in comparison to neat PHBV due to a better dispersion of the fibers in the matrix, as confirmed by atomic force microscopy (AFM) images.

Article

19 February 2025

The Effect of Polyethylene Glycol on Cobalt Oxide Nanoparticles Prepared Using Sonochemical Synthesis

In this work, Cobalt oxide nanoparticles (Co3O4·NPs) were synthesized via a simple sonochemical reaction by using polyethylene glycol (PEG) as a surfactant. Structural, morphological and spectroscopic analysis of obtained powder (Co3O4·NPs) was investigated by X-ray diffraction, FTIR spectroscopy and scanning electron microscope (SEM). The nanocrystalline nature of the sample was confirmed by XRD, which exhibits the cubic face-centered normal spinel structure of (Co3O4·NPs) and the space group of Fd-3m with the average crystallite size around 15 nm. FTIR spectrum shows two strong absorption bands of (Co+2O) and (Co+3O) which confirm the spinel structure of Co3O4·NPs. Moreover, SEM micrographs showed that the agglomeration of the nanoparticles was reduced by the addition of (PEG) surfactant and UV-Vis was used to study the synthesized material’s optical properties. The Co3O4 band gap ranged around 2.2 and 3.5 eV.

Article

27 February 2025

Thermophysical Properties of Polyamide 6 and High-Density Polyethylene Blends (Part 1. Without Compatibilization)

The structure and thermophysical properties of polymer blends polyamide 6/high-density polyethylene with component ratios of 70:30, 45:55 and 30:70, which not only provide phase inversion of the blended polymers, but also the formation of an interpenetrating network, have been investigated by differential scanning calorimetry, scanning electron microscopy and light flash method. The data on the influence of blends composition on their mechanical properties, density, structure, temperature, as well as melting and crystallization heats of polymer components have been obtained. The regularities of changes in thermal diffusion, heat capacities and thermal conductivity coefficients of polyamide 6 and high-density polyethylene individually and as part of the blends in dependence on their composition and temperature have been established. A nonlinear increase of the thermal conductivity coefficient from temperature was revealed when melting a more easily melting component of the blend. It was found that the maximum increase in thermal conductivity occurs in the blend forming an interpenetrating network. A possible way of creating composites with adaptive thermal conductivity by melting one of the components of the blend is proposed.

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