Australia is renowned for its highly variable rainfall patterns, which make it a continent marked by both droughts and flooding rains. With global warming driving atmospheric warming and altering weather systems, this variability is projected to intensify. Despite this, the specific trends and extent of rainfall changes across the country remain uncertain. Within this context, in this study, the temporal variability of rainfall in Australia was examined at annual, seasonal, and monthly scales using rainfall data spanning 1920 to 2020. Specifically, non-parametric tests were employed to assess the magnitude and significance of rainfall trends across 505 rainfall series within the Australian region. Results showed a widespread increase in rainfall in summer and spring throughout the study area. By contrast, autumn and winter showed a marked decrease in rainfall, with the greatest evidence along the Queensland coast and in southern Western Australia. If these trends are confirmed in the coming years, these deficits could limit water resources, affecting agricultural areas, the conservation of natural areas, and national parks. In addition, these changes in rainfall could increase the risk of droughts and wildfires, which could also have socio-economic impacts.
Measured against the legally binding international climate targets, climate policy must be massively accelerated on a worldwide scale. In the absence of effective global policy instruments, a central role can be played by combinations of regional quantity governance systems, such as the EU Emissions Trading System, and additional border adjustments, such as the newly established EU Carbon Border Adjustments (CBAM). This is to avoid mere emissions shifting to other states, to encourage these states also to pursue ambitious climate protection, and to avoid competitive disadvantages for domestic industries. This paper analyzes the ecological effectiveness of the CBAM—measured against the Paris climate targets—and its compatibility with world trade law. It combines a qualitative governance analysis with methods of legal interpretation. It is demonstrated that the CBAM does not raise any concerns under WTO law and can be classified as an ecologically effective measure supporting ambitious climate protection. However, the faster and more consistent introduction of the CBAM would be ecologically more effective.
This study explores, through mathematical simulation and Geographic Information Systems, the electricity production potential of Marine Renewable Energies (MRE) on the Cameroonian coast. The study uses data from the National Institute of Cartography and, in the absence of in situ oceanographic observation, data from the National Oceanic and Atmospheric Administration and those of Copernicus Marine Services, to determine and identify, after calculations on Excel and spatial representation on ArcGIS 10.2.2, areas with high MRE potential. The analyses carried out show that the Cameroonian coastline is full of significant potential for the development of MRE. Indeed, with a potential of approximately 6 kW at sea and approximately 1 kW on the coast, current energy constitutes a capitalizable opportunity. Concerning wave energy, the average production potential of the Cameroonian marine area is approximately 3.37 kW/m. However, it is much higher on the Kribi coast (between 4 and 7 kW/m). Furthermore, significant potential for tidal energy can be identified in the Wouri estuary, as well as in other sectors such as marine thermal energy and osmotic energy, although this requires further analysis to be better understood. These results would help promote research on these energies in Cameroon.
Drones, or unmanned aerial vehicles (UAVs), are increasingly utilized across diverse fields such as agriculture, environmental analysis, and engineering due to their ability to capture high-quality multispectral imagery. To ensure the accuracy of these images, radiometric calibration of onboard multispectral cameras is essential. This study aimed to develop and calibrate a low-cost Lambertian surface using barium sulfate (BaSO4) for radiometric calibration of UAV-mounted multispectral cameras. A stainless steel mold was designed to compact BaSO4, and the resulting surface was calibrated using an ASD FieldSpec HandHeld UV/NIR spectroradiometer and a Spectralon plate as the reference standard. Results showed a strong correlation (Pearson’s r = 0.9988) between the BaSO4 surface and the Spectralon plate, confirming that the BaSO4-based surface is a cost-effective alternative for producing diffuse Lambertian surfaces with performance comparable to the standard.
The Houston toad (Bufo [=Anaxyrus] houstonensis) is an endangered amphibian species that occupies a small range in Texas, USA. Despite recent increases in juvenile detections, obtaining data is limited by a narrow temporal window of juvenile emergence. This necessitates the rapid collection of ecological data. Because of this, we seek to test the quality of image-based measurements as an alternative to assessing the body condition of Houston toads. We used caliper- and image-based measurements of wild-caught adult toads and captive-bred juveniles, while recording handling time for each method with the juveniles. We compared scaled mass indices (SMI) and residuals from ordinary least squares regressions (OLS) between methods and life stages. Handling time of juvenile toads was significantly lower (p < 0.0001) for the image-based trial than the caliper-based trial. While SMI values violated key assumptions for a valid Condition index (CI), OLS condition index values did not. OLS condition values from the image-based trial were also not statistically significantly different to those from the caliper-based trial. These observations suggest that our image-based measurement technique is a valuable alternative to gaining morphometric data, and that applying this data to an OLS residual index is a more appropriate approach to monitoring individual- and population-level health in Houston toads.
Although performing lung biopsies on hospitalized patients with interstitial lung disease (ILD) has risk, initial studies have shown transbronchial lung cryobiopsy (TBLC) may be safely performed in this patient group. Data evaluating the value of this intervention in establishing a diagnosis and impacting management is lacking. We present a comparison of TBLC for inpatients and outpatients and provide data on the impact on medical therapy initiation and wait times from consultation to biopsy and treatment. Demographic data, pulmonary function values, chest imaging patterns, procedural information, diagnosis, and medical therapy changes, defined as medication initiation, adjustment, or cessation guided by TBLC results, were recorded from enrolled patients with newly identified ILD. Changes in medical therapy were the primary outcome. Time from consultation to biopsy and treatment was the secondary outcome. Fifty-four (54) patients (40 outpatient, 14 inpatient) were included. Inpatients underwent biopsy 2.5 ± 4.4 days after consultation compared to 15.5 ± 16.1 days for outpatients (p < 0.001). Medical therapy changes occurred 10.3 ± 7.9 days after biopsy for inpatients compared to 34.6 ± 37.0 days for outpatients (p < 0.001). There were no significant differences in medical therapy changes between the groups (p = 0.45). Our initial study suggests that performing TBLC on inpatients with newly identified ILD decreases wait times to treatment initiation and diagnosis. Efforts to understand the impact of a decreased wait time on ILD prognosis, including the development of progressive disease or fibrosis, symptom evolution, and quality of life, require further evaluation.
The aim of this study was to evaluate the fermentation dynamics of two wild hydrolytic microorganisms and their effect on the flow behavior of a culture medium formulated with Opuntia ficus-indica cladode flour. Identified Acinetobacter pitti and Bacillus subtilis presented maximum values of specific hydrolytic activity (SHA) at 24 h of growth (0.21 ± 0.05 and 0.22 ± 0.01 IU, respectively). The apparent viscosity of cladode flour medium (CFM) measured by applying shear rates (66.7 s−1–0.003 s−1) in suspensions (20%) showed a significant decrease (60%) as a function of bacterial growth progressed. After fermentation, the CFM exhibited pseudoplastic (shear-thinning) behavior, which was linked to the enzymatic degradation of polysaccharides. The use of crude extracellular enzyme extracts from these wild bacteria effectively reduced medium viscosity by breaking down the plant matrix. These findings highlight the hydrolytic potential of native strains in modifying the rheological properties of cactus-based culture media, offering a low-cost alternative for biomass pretreatment and valorization in future biotechnological applications.
Spherical calcium carbonate particles were prepared with sodium carboxymethyl cellulose (CMC) as an addition agent by using a double decomposition reaction. We studied the effects of the additional amount of CMC on the morphology and crystal forms of calcium carbonate. The morphology and size of the product were characterized by using a scanning electron microscope (SEM). We found that with the continuous increase of the additional amount of CMC, the number of prepared spherical calcium carbonate particles gradually increases. When the additional amount of CMC is 50% of the mass of calcium carbonate generated by the reaction, all calcium carbonate becomes micron-scale spherical calcium carbonate particles. The method can be used for the preparation of spherical calcium carbonate. The X-ray diffraction (XRD) was used to test the crystal form of calcium carbonate prepared by adding different qualities of CMC. It has been found that both calcite type and vaterite type calcium carbonate exist, but with the increase of the additional amount of CMC, the number of fingerprint peaks and amplitude deviated from the baseline increased gradually. These results show that the proportion of amorphous calcium carbonate is significantly increased as the additional amount of CMC increases. The study provides a reference for exploring the preparation conditions of calcium carbonate microcapsules and the mechanism of crystal form transformation.
Accurate and reliable estimation of the thermodynamic and transport properties of refrigerants is of paramount importance for the effective design and optimization of refrigeration cycles. In the context of growing environmental concerns, there is a pressing need to transition towards more environmentally benign refrigeration systems and applications. This imperative has driven the search for alternative refrigerants with reduced environmental impact. The refrigerant R452B has emerged as a promising candidate, particularly as a suitable replacement for R410A, due to its favorable thermodynamic characteristics and significantly lower Global Warming Potential (GWP). This research addresses the critical need for precise property data by developing mathematical models for key thermodynamic and transport properties of the R452B refrigerant. Specifically, the study focuses on modelling enthalpy, entropy, specific volume, thermal conductivity, viscosity, and thermal diffusivity. These properties are fundamental to understanding the behavior of the refrigerant within refrigeration systems and are essential for accurate system design and performance prediction. To achieve this modelling objective, the genetic expression programming (GEP) methodology, a powerful evolutionary algorithm capable of automatically generating complex mathematical expressions, was employed. GEP was selected for its ability to discover intricate relationships between variables and to produce explicit equations that can be readily implemented. The accuracy and reliability of the developed GEP models were rigorously evaluated. The coefficient of determination (R2) for the predicted thermodynamic and transport properties across a range of temperatures was found to be between 97% and 99%. This high degree of accuracy demonstrates the robustness and predictive power of the generated equations. The strong correlation between the model predictions and the actual property values indicates that these equations are sufficiently sensitive and accurate to be used with confidence in engineering calculations and simulations. The newly developed mathematical models offer a valuable tool for engineers and researchers working with R452B. These models provide a means to accurately estimate the thermodynamic and transport properties of this refrigerant without the need for complex and time-consuming experimental measurements or computationally intensive simulations. By providing dependable equations, this study facilitates more efficient and accurate design, analysis, and optimization of refrigeration systems utilizing the R452B refrigerant.
Chronic inflammation is widely considered a risk factor for T2DM by inducing insulin resistance, but all attempts to translate the concept into clinical therapies have failed in the past 30 years. Anti-inflammatory medicines, including anti-TNF-α antibody (Etanercept), anti-IL1 antibody (Anakinra), anti-IL6 (Ziltivekimab), and NLRP3 inflammasome inhibitor (Colchicine) have excellent activities in the control of inflammation in arthritis. They reduced inflammation in T2DM patients in the clinical trials, but none improved insulin sensitivity. Some of them exhibited a mild and transient activity in the control of blood glucose, but the activities were related to the improvement of insulin secretion by β-cells. The failure may be related to followings: over-interpretation of TNF-α activity; ignoring the role of anti-inflammatory cytokines; differences between mice and humans. However, the species difference cannot fully explain the failure as these therapies did not work in the animal models as well. Moreover, genome-wide association studies (GWAS) show that T2DM is not associated with proinflammatory cytokine genes, including TNF-α, IL-1β, IL-6, and CCL2(MCP1). More studies suggest that inflammation has beneficial activities in the mobilization of energy stores and promotion of energy expenditure to prevent energy surplus, a risk factor of obesity-associated T2DM. Inflammatory cytokines induce lipolysis, thermogenesis, and satiety. In this regard, the inflammatory response is a compensatory event to obesity-associated stress with beneficial effects on energy metabolism. It is time to reconsider inflammation activity in obesity for protective activities.