New Model of Multicomponent Raw Materials and Its Use in Intensifying Hydrotreating Process of Diesel Fuel

Hydrotreating of diesel fuel aims to reduce the sulfur content in the fuel to 10 ppm to meet environmental standards. However, this deep purification of diesel requires the use of expensive catalysts at hydrotreating plants with giant reactors with a capacity of 200–600 cubic meters. Such large volumes of reactors are associated with classical kinetic methods for chemical reactions, where the feedstock is in the reactor until the required conversion depth is reached. All known mathematical models for diesel hydrotreatment have a common drawback: they rely on approximations about the composition of multicomponent raw materials containing dozens of different organic sulfur compounds that react differently in hydrogenation reactions. This raw material is often presented in a mathematical model as a combination of two to six pseudo-components or lumps combining organosulfur impurities from one or more homologous groups. This theoretical basis allows us to simulate the current state of hydrotreating technology, but does not develop and promote it. We propose a new approach to mathematical modelling of diesel fuel hydrotreating, in which the structure of the mathematical model considers the composition of raw material as a set of 10–20 narrow fractions. The set of hydrogenated organosulfuric impurities within each fraction is treated as a single pseudocomponent. This allows us to integrate the system of differential equations of the model and adapt the rate constant to the concentration of hydrogenated organosulfur impurities at any given time during the process. The developed model has also allowed us to propose a new technology, hydrotreatment: separating the feedstock into two or three wide fractions, combining the corresponding narrow fractions, and then subjecting them to individual hydrogenation processes. As a new approach, this differential hydrotreatment technique will reduce the catalyst load in the hydrotreatment unit by approximately 50%, while maintaining efficiency of processing, or double efficiency while maintaining a similar catalyst load using traditional technology.

Unpacking the Transformative Power of the Rights of Nature: Rethinking Self, Society, and Nature in Environmental Governance in Tanzania

This study examines the transformative potential of integrating the Rights of Nature (RoN) into Tanzania’s environmental governance framework to address persistent ecological degradation, legal marginalization of local communities, and systemic governance gaps. Despite global progress in adopting the Rights of Nature (RoN), where ecosystems are granted legal personhood and communities serve as guardians Tanzania’s legal and institutional frameworks remain predominantly anthropocentric, lacking provisions that recognize nature’s intrinsic value. The primary objective of the study was to critically evaluate the extent to which Tanzania’s current governance systems reflect or exclude RoN principles and to propose transformative pathways grounded in justice, inclusivity, and local knowledge. The study analyzed international legal instruments, Tanzanian statutes, scholarly literature, and case studies using a doctrinal and thematic review methodology. Findings reveal that, despite Tanzania’s comprehensive environmental legislation, such as the Environmental Management Act (2004), key provisions fail to ensure procedural justice and exclude communities from meaningful participation, particularly under Strategic Environmental Assessment regulations. Conversely, local and Indigenous communities such as the Maasai, Chagga, and Zaramo have long practiced ecological stewardship grounded in relational worldviews, echoing RoN values. However, these systems are neither legally recognized nor institutionalized. The study concludes that a shift towards rights-based and transformative governance is necessary to address environmental injustice and ecological decline. It recommends revising legal frameworks to grant ecosystem rights, mandating participatory governance, and embedding Indigenous and local knowledge into environmental policy. Such reforms will not only enhance ecological integrity and local empowerment but also contribute to achieving Tanzania’s commitments under Sustainable Development Goals (SDGs) 13, 15, and 16.

iMed: A Global Academic Platform for Innovation, Medical Research and Translation

Beyond Genetics: Exploring Aspects of Non-Biological Kinship in Prehistoric Times

This article explores alternative ways of conceptualizing kinship in prehistoric contexts beyond the confines of genetic reductionism. While ancient DNA research has revitalized interest in the archaeology of kinship, it often privileges patrilineal or matrilineal models and risks obscuring forms of relatedness not grounded in biological ties. Drawing on comparative anthropological models and archaeological case studies, the paper highlights the complexity of kinship as manifested in practices of adoption, fosterage, commensality, co-residence, and non-biological affiliation within (non)nuclear households. By integrating socio-cultural, economic, and material dimensions, it demonstrates the diverse methodological and theoretical approaches necessary to move beyond descent-centered reconstructions. The discussion advocates for an interdisciplinary framework that challenges reductionist assumptions and opens new avenues for understanding relatedness in the deep past. Finally, the article emphasizes the village as a unit of analysis within a multi-scalar approach. It presents future directions and archaeological correlates of adoption, child circulation, and fosterage derived from archaeological, genetic, and ethnographic evidence.

Sulfatide Inhibits Growth of Fibroblasts and Is a Potential Treatment against Fibrosis

Fibrosis of vital organs such as the lungs, liver, and kidneys is a serious condition without effective causal treatment. Here, we suggest the use of the sphingolipid sulfatide and its isoform C16, which we have found to inhibit the growth of fibroblasts. In the lungs, sulfatide can be easily administered via an inhalation spray. Alternatively, fenofibrate, an anti-cholesterol drug with no major side effects, may be used, as it enhances the body’s own production of sulfatide.

Divergent Aging Mechanisms of Calcium Arsenic Residue under Dry-Wet and Freeze-Thaw Cycles: Toxic Metal Mobility, Multiscale Physicochemical Characterization, and Escalated Ecological Risks

This study investigates the long-term mobility and ecological risks of As, Zn, and Cd in calcium arsenic residue (CAR) under simulated dry-wet (DW) and freeze-thaw (FT) cycles. Accelerated aging experiments, combined with multiscale characterization (XRD, XPS, SEM, FTIR), revealed distinct transformation mechanisms. DW cycles promoted carbonate-driven dissolution, As(III) oxidation to As(V) (resulting in an 18.4% increase in As(V) as shown by XPS), and sulfide oxidation (with reductions of 47.7% in ZnS and 15.08% in CdS). These processes increased the acid-soluble metal fractions (F1: As by 11.3%, Zn by 6.0%, and Cd by 8.7%) and metal release rates (52.39% for As, 42.63% for Zn, and 68.55% for Cd under DW conditions). In contrast, FT cycles induced mechanical fracturing and ice-mediated stabilization, which limited ion migration, partially amorphized ZnO, and promoted the precipitation of Cd(OH)₂. Ecological risk assessments indicated rising risks, with integrated potential ecological risk indices (IPER) reaching 11,187.85 under DW conditions and 10,668.29 under FT conditions, with arsenic contributing over 80%. The Risk Assessment Code (RAC) reclassified all metals into moderate-risk categories (As: 11.9–19.7%, Zn: 9.4–15.2%, Cd: 12.1–18.6%). Weibull modeling (α = 6.98–10.98, R² > 0.96) described the nonlinear kinetics, showing that cadmium aged the fastest (λ: Cd > As > Zn), with delayed but persistent risks under FT conditions. These results underscore the importance of developing climate-resilient stabilization strategies. The integrated framework combining mineral evolution, kinetics, and risk forecasting offers significant insights for managing legacy CAR pollution under changing climate conditions.

Enhancing Ablation Resistance of C/C-HfC-SiC Composites by In-Situ Growth of HfC Nanowires

C/C-HfC-SiC composites are promising ablation-resistant ultra-high temperature thermal protection materials. To further enhance their performance in extreme thermal environments, the introduction of HfC nanowires (HfC_NWs) into the composite has been identified as an effective strategy. The quantity and morphology of the introduced HfC_NWs significantly influence the ablation resistance of the composites. In this study, by controlling the concentration of Ni salt during the hydrothermal synthesis process, the loading amount of Ni catalysts on the surface of carbon fibers was regulated, thereby achieving control over the quantity and structure of HfC_NWs in the C/C-HfC-SiC composites. It was found that a low Ni loading facilitates the growth of sparse and slender HfC_NWs. As the Ni loading increases, the number of HfC_NWs rises, gradually evolving into a high-density, multi-oriented network structure. However, excessive Ni tends to induce short, thick, and clustered growth of the nanowires. Based on this, three types of HfC_NWs-modified C/C-HfC-SiC composites were prepared using the polymer impregnation and pyrolysis (PIP) process. The quantity and diameter of the HfC_NWs significantly affect the ablation resistance of the composites. Among them, the composite prepared with a 4.38 wt% Ni loading exhibited excellent ablation resistance, with mass and linear ablation rates of 0.47 mg·s⁻¹·cm⁻² and 5.50 μm·s⁻¹, respectively. The performance improvement is attributed to the formation of a continuous HfO₂ skeletal structure after the oxidation of an appropriate amount of HfC_NWs. This continuous HfO₂ skeleton significantly enhances the ability of the oxide layer to resist high-speed gas flow erosion and oxygen penetration. This study can provide support for the design of HfC_NWs-reinforced C/C-HfC-SiC composites and promote their engineering application in the field of aerospace thermal protection.

Bioenergy Technology and Carbon Intensity in U.S. and China: Threshold Roles of Capital Accumulation, Education and Inequality

Bioenergy technology holds significant promise for reducing carbon intensity and fostering sustainable development, yet its impact remains unclear. This article employs both a panel threshold model and a random forest model, analyzing data from the primary administrative regions in the United States and China to explore the threshold effects and regional heterogeneity of bioenergy technology on carbon intensity, where the bioenergy technology is measured using patent data. In the United States, the impact of bioenergy technology on carbon intensity initially shows a positive effect, which later turns negative as per capita capital stock increases. The technology’s inhibitory effect strengthens with higher levels of education but becomes insignificant as the Gini coefficient rises. In China, increasing per capita capital stock shifts the impact of bioenergy technology from negative to insignificant, while higher education levels enhance its inhibitory effect. The Gini coefficient, however, does not significantly affect the impact of technology. Additionally, these threshold effects exhibit notable regional variations. The study provides cross-country evidence of how institutional and structural conditions shape the carbon mitigation effects of bioenergy technology, offering practical insights for policies that combine trade facilitation, education, and inequality reduction with low-carbon energy transitions.

Book of Abstracts—The 10th International Symposium on Sturgeons (ISS10)

Electrical Characterization, Optical Micrographs, and the Compositional Analyses of Al-Glass/C-Glass Composites

This report shows the resistance (r) of Carbon-Glass composites and the Current/Voltage (I-V) characterization of Al-Glass composites. The optical micrographs and elemental determination of Carbon-Glass and Al-Glass are in this record. The effects of pressure and the influence of particle size on the electrical properties of these composites are included. The sample area, thickness range, and particle size are respectively 34.0 × 35.0 mm², 20.8–22.10 mm, and 100 µm. The constituents of the same particle size were made into solids by applying a pressure of 30 MPa. The results obtained from examinations showed that the composition of Al in glass, compaction pressure, and particle size significantly influenced the resistance and the electrical I-V relationship of the compacted materials. The electrical properties of samples are within the range of 10–50% weight of Al in composites, and 0–100% weight of carbon in composites. The resistance of Carbon-Glass is sinusoidal with Mega Ohms values. The current variation of Al-Glass composites is also a sine wave in the I-V display, which is between 0 and 10 µA. The Current-Voltage notation is with sinusoidal resolution for Al-Glass composites. The voltage range is from −0.5 V to 1.0 V.