High-speed rail (HSR) has revolutionized global transportation by providing fast, reliable, and efficient city-to-city travel. While its urban benefits are well-documented, the potential advantages for rural development are often overlooked. The high-speed rail project on the Naples-Bari route in Southern Italy aims to connect the urban centers of Naples in Campania and Bari in Apulia, traversing inland and rural areas. Initiated in 2016 and planned for completion in 2028, this project is anticipated to deliver numerous benefits. The purpose of this research is to examine the largely overlooked high-speed rail (HSR) in Southern Italy from an economic and territorial perspective and to determine whether it can sustainably promote rural development in the areas along the railway line. This study examines whether the HSR line will enhance economic activities, strengthen industries, and improve spatial accessibility in rural areas. Using a 2020 dataset covering 25 municipalities along the railway line, including those with stations and construction sites projected to open by 2024, three regression models were employed to estimate potential improvements in income and employment. The findings indicate mixed results: access time to airports improves, decreasing by 7%, while access to ports does not see similar benefits. Income shows a positive correlation with HSR, increasing with population growth around stations, suggesting a trend towards urban agglomeration. However, the study underscores that HSR is not universally beneficial for rural economies and that supportive development networks are crucial. Policies should adopt short-term strategies to strengthen future HSR projects and prepare for the anticipated surge in mass tourism to rural areas.
To meet the high-quality requirements for clean steel production and fully exploit the performance advantages of carbon-containing refractories, nanomaterial has been introduced into the matrix to develop advanced carbon-containing refractories. Nanomaterials, as critical additives, play a crucial role in developing novel refractories. The service performances of carbon-containing refractories are affected not only by their physical and chemical properties but also by their microstructure. This review provides a comprehensive overview of the latest research on oxide-carbon composite refractories containing nanomaterials, categorized by their composition: nanocarbons, nano oxides, and nano non-oxides. Incorporating nanomaterials can enhance the service performances of the refractories, optimizing phase composition and microstructure. Furthermore, future research directions in nanomaterial technology for carbon-containing refractories are discussed.
Lithium batteries pave way for rapidly reducing greenhouse gas emissions. Still there are concerns associated with battery sustainability, such as the supply of key battery materials like cobalt, nickel and carbon emissions related to their manufacture. While LiMn2O4 spinel is a common cathode material for Li-ion batteries that remove Co and Ni, studies on over-stoichiometric variants and their behavior across a broad potential range may be limited. Research in this area could provide valuable insights into the performance, stability and electrochemical characteristics of such cathodes, offering potential benefits for the development and optimization of Li-ion battery technologies. This study investigates the electrochemical behavior of Li-rich Li1+yMn2−yO4−δ (LMO, y ≈ 0.03, δ ≈ 0.01) spinel as a cathode in Li-ion batteries, focusing on the phenomenon of extra capacity under the extended operating voltage 1.5–4.8 V vs. Li+/Li. The nanostructured LMO sample synthesized by sol-gel method and calcined at 900 °C is characterized by X-ray diffraction, scanning and transmission electron microscopy and surface area measurements. The Li-rich spinel electrode delivers a specific discharge capacity of 172 mAh g−1 at 1st cycle. It retains 123 mAh g−1 at the 100th cycle (71.5% capacity retention) at current density of 100 mA g−1 current density (i.e., ~0.7 C rate). An excellent stability is obtained in the 1.5–4.8 V potential window, with a discharge capacity of 77 mAh g−1 after 500 cycles at the same current density, owing to the reduction of the Jahn-Teller effect by Li doping. These results contrast with the specific capacity of 85 mAh g−1 (1st cycle) and the capacity retention of 54.3% after 100 cycles, obtained when the cell operates in the narrow potential range of 3.0–4.5 V.
Background: Coarctation of the aorta is a frequently diagnosed congenital heart defect and often requires surgical repair in early infancy. Infants born with this condition remain at risk for post-operative morbidity and reintervention within the first year of life. Methods: A single-center, retrospective chart review was performed. The protocol was approved by the Institutional Review Board (IRB-21-156, 14 August 2021). A 10-year review from January 2010 to December 2020 identified all children diagnosed with coarctation of the aorta or arch hypoplasia; without any associated major congenital cardiac pathology (i.e., simple coarctation). Reintervention-free-survival at one year for all infants who underwent surgical repair was assessed. Patient characteristics for those who did and did not experience significant adverse event (SAE) in the postoperative period were obtained and compared. Results: A total of 105 patients diagnosed with isolated coarctation of the aorta or arch hypoplasia and who underwent surgical repair were identified. Of these, 11 patients (10%) experienced a SAE (i.e., vocal cord palsy, diaphragm palsy, chylothorax, stroke/neurological complication, need for reintubation or tracheostomy, necrotizing enterocolitis, major bleeding or thrombotic vascular complication, or reintervention) in the post-operative period. Patients who experienced a SAE were more likely to have a prenatal diagnosis of coarctation of the aorta (p = 0.03), a known genetic anomaly (p = 0.0001), or had undergone a median sternotomy approach/complex arch repair (i.e., requiring patching of the aorta) (p = 0.0001). Genetic anomaly (mainly Turner syndrome) was the only independent predictor of SAE in multivariate analysis (OR = 6.7) Follow up data at one year was available for 79 patients, with only 6 patients requiring reintervention before 1 year of age. Conclusions: Overall, infants who undergo surgical repair of simple coarctation of aorta have an excellent chance of reintervention-free-survival at one year post intervention. Those with a known genetic anomaly or requiring median sternotomy approach appear to have a higher risk for a SAE in the postoperative period.
This paper proposes a distributed reinforcement learning method for multi-robot cooperative target search based on policy gradient in 3D dynamic environments. The objective is to find all hostile drones which are considered as targets with the minimal search time while avoiding obstacles. First, the motion model for unmanned aerial vehicles and obstacles in a dynamic 3D environments is presented. Then, a reward function is designed based on environmental feedback and obstacle avoidance. A loss function and its gradient are designed based on the expected cumulative reward and its differentiation. Next, the expected cumulative reward is optimized by a reinforcement learning algorithm that makes the loss function update in the direction of the gradient. When the variance of the expected cumulative reward is lower than a specified threshold, the unmanned aerial vehicle obtains the optimal search policy. Finally, simulation results demonstrate that the proposed method effectively enables unmanned aerial vehicles to identify all targets in the dynamic 3D airspace while avoiding obstacles.
The scientific article analyzes the dynamics of textile industry production in the USSR and the Russian Federation from 1985 to 2022 years.The article provides a fairly complete overview of modern methods of forecasting the development of objects, mainly based on time series analysis, including issues of forecasting cyclic and discontinuous processes, forecasting multidimensional objects with a correlated system of indicators. Authors calculate the forecast until 2026 year based on a bank of mathematical forecasting models implementing various monotonic nonlinear transformations both along the ordinate axis and along the abscissa axis. The criterion of the minimum variance of the forecast error was used as a criterion for selecting a specific model from the bank. The scientific value of the article lies in the fact that, for the first time, it offers a criterion for choosing a mathematical model from a set of them, which uses the minimum estimate of the variance of forecast errors for this model. This work can be considered a step towards the creation of artificial intelligence since the selection of the optimal model for a specific time series allows to obtain a training sample for it, which is fundamentally impossible to obtain without it.
This paper presents a methodology for fast-track documentation of landscape alterations before and after natural hazards, specifically focusing on the impacts of storms Daniel and Elias (2023) in Northern Euboea, Greece, which flooded larger areas than the storm Zorbas (2018). This happened because the plane trees had been affected by the disease Ceratocystis platani and had dried up, and the forest had burned. Therefore, the water moved faster, and in recent storms, the riverbed widened. This research aims to capture the transformed landscape rapidly by utilizing modern mapping technologies, including Google Earth, digital terrain models and drone-based photogrammetry. The methodology involves on-site inspections and the creation of three-dimensional models to document and analyze the affected areas. This approach facilitates a more comprehensive understanding of how the landscape can dynamically change due to a natural disaster. It highlights the importance of the on-site landscape inspection with sophisticated tools based on commercial equipment and open-source software.
This research highlights the governance of landscape and policy coherence to ensure a sustainable supply of ecosystem services through incentives for ecosystem schemes at the municipal level in Nepal. The study was carried out in Dhankuta and Dasarath Chand municipalities representing Nepal’s Koshi and Sudur Paschim provinces. Six aggregate governance indicators adopted by the World Bank Group were assessed through interviews with primary stakeholders of selected landscapes in two municipalities, followed by Key Informant Interviews. The study indicates that implementation of the Incentive for Ecosystem service scheme is feasible, creating multi-stakeholder institutions at the local level. However, there are several governance challenges to ensure its success. In particular, incentives for ecosystem schemes must be part of local government planning, where multisectoral coordination and collaboration are essential. While municipal authorities have constitutional jurisdictions to initiate such schemes, they lack the human resources to understand ecosystem management for a sustainable supply of ecosystem services. Therefore, landscape governance is essential to make incentive schemes successful and ensure transparency and equitable benefits among ecosystem service providers.
Photocatalytic (PCO) and photothermocatalytic oxidation (PTCO) of ethene (C2H4) and ethanol (EtOH) are investigated using TiO2 and 1%Pt/TiO2 coating on velvet glass support in the presence of UV-A and UV-C irradiation. Both VOC are efficiently mineralised under UV-A irradiation and PCO, but the presence of Pt has a minor impact on their transformation. Instead, there is only a slight increase in the disappearance of EtOH and the formation of acetaldehyde, which are already observed in the dark. Surprisingly, when a higher photon flux is emitted with a UV-C lamp, photocatalytic disappearance and mineralisation of EtOH are less effective than under UV-A irradiation in the presence or absence of Pt. Similar behaviour is also observed on C2H4 PCO in the presence of 1%Pt/TiO2 but not on its PCO mineralisation with TiO2, which is improved by a factor equivalent to the number of photons emitted. Under PTCO, by increasing the temperature from 40 °C to 120 °C, only a benefit impact is observed on C2H4 and EtOH disappearance but an important decrease of mineralization of C2H4 was observed in presence of TiO2 and UV-C The behaviour of these two VOCs under different irradiations and temperatures will be discussed according to the catalytic process.
Laser Additive Manufacturing (LAM), an avant-garde technology in manufacturing, harnesses the precision of laser energy to fabricate intricate parts through the meticulous process of melting and subsequently depositing layers of metal powders. Among the esteemed materials employed, 316L stainless steel (316L SS) stands out for its unparalleled corrosion resistance, exceptional high-temperature tolerance, and remarkable creep strength, making it a ubiquitous choice in the aerospace, medical, and nuclear power sectors. LAM has distinguished itself in the fabrication of intricate 316L SS components, yet enhancing the metallurgical bonding strength within these structures remains a pivotal area of ongoing research. This research endeavor delves into the intricate microstructure and mechanical properties that characterize the interface between the LAM-produced 316L SS cladding layer and its substrate, further investigating how varying laser energy densities (E) subtly influence these properties within the additive manufactured components. Remarkably, the interface region exhibits a tensile strength of 615.1 MPa, surpassing that of both the deposited layer and the substrate by 5.4% and 7.4% respectively, underscoring a robust bond between the two layers. This investigation not only sheds light on the unique process capabilities and performance merits of LAM in crafting 316L SS cladding layers but also pioneers novel approaches and conceptual frameworks for bolstering the metallurgical bonding strength of this esteemed material. As such, it constitutes a treasure trove of insights for subsequent research endeavors and practical applications across related disciplines.