Production of Highly Modified C₃₀-carotenoids with Singlet Oxygen-quenching Activities, 5-glucosyl-5,6-dihydro-4,4’-diapolycopen-4’-oic Acid, and Its Three Intermediates Using Genes from Planococcus maritimus Strain iso-3

Planococcus maritimus strain iso-3 was previously isolated from intertidal sediment in the North Sea and was found to produce a highly modified C₃₀-carotenoid, methyl-5-glucosyl-5,6-dihydro-4,4’-diapolycopenoate, as the final product. In this study, we analyzed the function of the carotenoid terminal oxidase crtP (renamed cruO) and aldehyde dehydrogenase aldH genes in P. maritimus strain iso-3 and elucidated the carotenoid biosynthetic pathway for this strain at the gene level. We produced four novel C₃₀-carotenoids with potent singlet oxygen-quenching activities, 5-glucosyl-5,6-dihydro-4,4’-diapolycopen-4’-oic acid and its three intermediates, which were obtained using E. coli cells carrying the cruO (and aldH) gene(s) in addition to the known P. maritimus carotenogenic genes.

Plasmon Enhanced Nickel(II) Catalyst for Photocatalytic Lignin Model Cleavage

Photocatalytic-induced cleaving of the ether C–O bond in model lignin compounds was studied with a closely-coupled compo-site material consisting of Ni(OH)₂ and gold nanoparticles (NPs) on a zirconia support (Au/ZrO₂–Ni(OH)₂). The three important ether bond types consisting of α-O-4, β-O-4, and 4-O-5 linkages can all be cleaved using this catalyst at reaction temperatures 40, 85 and 95 °C when under low-flux visible light irradiation. The Au NPs action as a light-harvesting antenna provided light-generated hot electrons that reduced Ni²⁺ to Ni⁰. The Ni⁰ was the active catalytic site where reductive cleavage of ether C–O bonds occurred while it was oxidized to Ni²⁺ to complete the catalysis cycle. The plasmonic antenna system with supported Ni(OH)₂ exhibited better ability for the catalytic reductive ether cleavages under visible light irradiation compared to photocata-lysts of Au NPs and Ni²⁺ ions immobilized on alumina fibers.

Metal-Free Lewis Pair Catalysts for a One-Pot Terpolymerization of Propylene Oxide, ʟ-Lactide and CO₂

Multiblock and di-/tri-block copolymers are successfully synthesized for the first time via the metal-free terpolymerization of propylene oxide (PO), ʟ-lactide (LA) and CO₂ in one-pot/one-step and one-pot/two-step protocols respectively. Firstly, triethyl borane (TEB) and bis(triphenylphosphine)iminium chloride (PPNCl) Lewis pair is employed in the ring-opening polymerization of LA, wherein the catalytic efficiency is significantly correlated to the TEB/PPNCl feed ratio. Next, a series of TEB/base pairs are selected to synthesize the PO/LA/CO₂ terpolymer (PPCLA) in one-pot/one-step strategy. In PPCLA synthesis, LA exhibits the fastest reaction rate but severe transesterification is almost unavoidable, resulting in low molecular weight products. In order to prepare high-molecular-weight terpolymers, a one-pot/two-step methodology has to be applied. By this method, the copolymerization of PO/CO₂ proceeds first to form poly(propylene carbonate) (PPC) macroinitiators, which triggers the polymerization of LA to polylactide (PLA), leading to PLA-PPC or PLA-PPC-PLA block copolymers. The synthesized PLA-PPC-PLA block copolymers display improved thermal stability compared with PPC.

Carbon Neutrality and Life Cycle Thinking

Climate change is one of the most critical sustainability challenges facing the humanity. International communities have joined forces to mitigate climate change impact and aim to achieve carbon neutrality in the coming decades. To achieve this ambitious goal, life cycle thinking can play critical roles. Specifically, life cycle thinking helps evaluate the true climate impacts to avoid shifting emissions across processes in a product life cycle. It can also help inform consumers with carbon footprint information to make climate-conscious choices. Finally, it can help identify key processes dominating the carbon footprint of a product so that future improvement can set priorities. High quality data is required for accurate and timely carbon footprint accounting and critical challenges exist to obtain and share such data.

Current Challenges to the Sustainable Development of Rural Communities in Russia's Central Chernozem Region

The rural community system in the Central Chernozem Economic Region in Russia is undergoing a radical transformation under the interrelated influence of fundamental factors that have rendered the development of many communities unsustainable. This paper analyses the role of urbanisation processes in population changes and transformation of rural community systems in the region; determines the level of horizontal mobility among the rural population, as well as its impact on settlement evolution; assesses the share of small and extremely small communities in settlement composition; and outlines these communities’ future development prospects. The authors believe that the socio-demographic “desertification” of peripheral municipalities can pose challenges to rural development: a shortage of labour resources, changes in population quality, and problems of innovation diffusion. The study recommends improving the comfort of the living environment and accelerating the technical re-equipment and automation of agricultural production.

Image Fusion Capability from Different Cameras for UAV in Cultural Heritage Applications

In this paper, image fusion is performed by utilizing images derived from different cameras for the unmanned aerial vehicle (UAV). By producing the fused image, the spatial resolution of the multispectral (MS) image is improved on the one hand and the classification accuracy on the other hand. First, however, the horizontal and vertical accuracy of the generated products, orthophoto mosaics, and digital surface models, is determined using checkpoints that do not participate in the processing of the image blocks. Also, the changes of these accuracies with a 50% increase (or decrease) of the UAV's flight height are determined. The study area is the Early Christian Basilica C and the flanking Roman buildings, at the archaeological site of Amphipolis (Eastern Macedonia, Greece).

A New Phase of Synthetic Biology and A New Journal for Its Twin with Engineering for Biomanufacturing

Fibrosis: A New Open-Access Journal to Share Your Research

Sustainable Polymer & Energy: A New Open-Access Journal to Share Your Research on Sustainable Polymer and Advanced Energy Materials

Drones and Autonomous Vehicles — A New Open-access Journal for Multidisciplinary Research on Autonomous Systems