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Article

23 July 2025

Evaluation and Modeling of Long-Term Endurance Measurement on Electric Double Layer Capacitors to Increase Reliability of Lifetime Predictions

Sustainability in the electrical industry and product reliability are fundamentally dependent on product lifetime predictions. Long-term DC voltage endurance measurements at two different temperatures on various commercial electric double-layer capacitors are presented, discussed, and used to develop a deterioration model suitable for estimating lifetime. Capacitors were tested under constant voltage for approximately 1 year at 65 °C and about 4 years at room temperature. To describe the deterioration in terms of capacitance and the equivalent series resistance, a phenomenological model is proposed and tested against measurements taken at room temperature. The proposed model is based on a general exponential relation with a time-dependent deterioration rate. The model is tested against long-term measurements with constant and time-dependent temperature acceleration factors. Analysis of capacitance and equivalent series resistance measurements shows a time or deterioration dependence in the temperature acceleration factor and different phases of deterioration.

Keywords: Electric double-layer capacitor; ECLC; Supercapacitor; Lifetime; Degradation; Long-term; Endurance; Modeling
Intell. Sustain. Manuf.
2025,
2
(2), 10023; 
Open Access

Communication

22 July 2025

The Importance of Methods in Assessing Conservation Status of Abundant Fish Species through Genetic Diversity Estimates

This study compares the accuracy of two genomic approaches in estimating genetic diversity levels, which could be useful for informing species conservation assessments of abundant, exploited fish species. The first approach (SNP-calling-based) is the commonly used pipeline of SNP calling followed by SNP filtering at a determined Minor Allele Frequency (MAF). The second approach (genotype-likelihood-based) does not perform SNP calling but estimates the Site Spectrum Frequency (SFS) based on alignment quality and sample size. The results show up to two-fold differences in the magnitude of the estimated nucleotide diversities among the analyzed datasets. The SNP-calling-based approach produces overestimates when missing data are considered in the analysis and shows pronounced deviations of the SFS towards high-frequency SNPs when filtering by MAF > 5%. The genotype likelihood-based approach showed that nucleotide diversity estimates significantly deviated from neutral expectations, as expected based on the known history of the case-study fish population analyzed here, regardless of whether missing data were considered. In contrast, the SNP-calling-based approach only shows this expected difference when no missing data are included and no MAF filtering is performed. Overall, the results indicate that using the SNP-calling-based approach may hide the effects of population size declines in abundant exploited fish species, while genotype-likelihood-based estimates of nucleotide diversity can effectively contribute to informing conservation assessments.

Keywords: Adaptive potential; Population genetics; Genomics; Fisheries; Climate change; Conservation
Ecol. Divers.
2025,
2
(3), 10007; 
Open Access

Article

21 July 2025

Rapid Production of High-Titer d-Mannitol and Gluconate Catalyzed by a Combination of Whole-Cell and an Enzyme at High Temperatures

d-Mannitol and d-gluconate are value-added biobased chemicals with diverse applications in food, medical, and chemical industries. d-Mannitol can be hydrogenated from hexoses (e.g., d-fructose) catalyzed by microbial fermentation, whole-cell biocatalysis, and purified-enzyme cascade biocatalysis. Here we designed a cell–enzyme system comprised of the whole cells co-expressing both hyperthermophilic mannitol dehydrogenase (MDH) and glucose dehydrogenase (GDH) as well as a hyperthermophilic xylose isomerase (XI). The whole cells have its inherent NAD enabled to implement NAD-self sufficient coupled redox reactions without externally-added NAD and aeration. Four cases of whole cells co-expressed MDH and GDH in E. coli BL21(DE3) were compared and optimized by expressing two genes separately or in tandem and changing gene alignment. Also, two-step biotransformation was developed to convert 300 g/L glucose to 129 g/L mannitol and 161 g/L gluconate in a pH-controlled bioreactor at 70 °C. This cell–enzyme system had a high volumetric productivity (10.7 g/L/h mannitol and 13.4 g/L/h gluconate) and a high product yield (91.7%). This study implied that using hyperthermophilic enzymes and cell–enzyme system could open great opportunities for industrial biomanufacturing.

Keywords: d-Mannitol; Gluconate; Whole cell catalysis; Thermophilic enzyme; NAD self-sufficient
Synth. Biol. Eng.
2025,
3
(3), 10011; 
Open Access

Review

21 July 2025

Fuel Oil Combustion Pollution and Hydrogen-Water Blending Technologies for Emission Mitigation: Current Advancements and Future Challenges

In recent years, researchers have focused on exploring alternative fuel technologies that enhance engine performance and combustion efficiency while reducing nitrogen oxide (NOx) and particulate matter (PM) emissions. Water-diesel emulsified fuel, which requires no engine modifications, has emerged as a critical pathway for cleaner diesel engine applications. This review systematically examines the combustion characteristics, emission performance, and energy efficiency of emulsified fuels in compression ignition (CI) engines. Studies indicate that compared to conventional pure diesel, emulsified fuels significantly optimize combustion processes through micro-explosion phenomena, shorten ignition delays, and improve combustion efficiency. Notably, NOx and PM emissions are simultaneously reduced, effectively resolving the traditional trade-off dilemma between pollutant reduction targets. Emulsified fuel exhibits comparable power output and fuel consumption rates to those of pure diesel, while delivering enhanced environmental benefits. Additionally, innovative technologies such as hydrogen nanobubbles further enhance combustion dynamics by improving fuel atomization and radical generation, though challenges persist in stabilizing non-aqueous nanobubbles and scaling up production. Despite ongoing advancements in policy incentives (e.g., green hydrogen subsidies) and combustion mechanism research, industrial adoption of emulsified fuels still faces technical hurdles, including equipment corrosion and issues with long-term storage stability issues. In conclusion, water-based emulsified fuels and hydrogen-water blending technologies provide efficient and low-cost transitional solutions for reducing diesel engine emissions, with their multi-component synergistic optimization mechanisms laying a theoretical and practical foundation for future clean fuel development.

Keywords: Water-diesel emulsified fuel; Hydrogen-water blending; Micro-explosion phenomena; NOx emissions; PM emissions; Synergistic optimization; Emission mitigation
Clean Energy Sustain.
2025,
3
(3), 10010; 
Open Access

Article

21 July 2025

The Intergovernmental Networks of Ecological Protection Policies Issuing Entities in the Source Region of the Yangtze River: A Case Study of Qinghai Province

Ecological conservation and governance play key roles in constructing an ecological civilization society, while intergovernmental cooperation provides new perspectives for cross-regional ecological governance. We employed a social network analysis (SNA) method to examine 110 published ecological policies from 2000 to 2024 in the Source Region of the Yangtze River (SRYR). The study has three key findings. Firstly, intergovernmental collaborative policies on ecological protection showed an upward trend, with intra-provincial collaborations within Qinghai Province being the most frequent. Secondly, four collaboration models were demonstrated, namely: national ministries, national and provincial, cross-provincial and intra–provincial collaborations. National agencies and Qinghai provincial agencies collaboratively set objectives, which Qinghai operationalizes with incentive-constraint measures. Then, the targeted guidelines were launched by national and provincial authorities. Afterward, cross–provincial agreements and mechanisms facilitate joint actions. Thirdly, we revealed the hierarchical structures, including a  national network, two central-local sub-networks, three-tier inter-provincial partnerships, and four regional sub-clusters. Core actors include national ministries that coordinate cross-departmental efforts. The Qinghai provincial government serves as a central-local hub. It maintains strong transboundary ties with Aba and Ganzi Prefectures of Sichuan Province. Provincial departments such as ecology and environment, forestry and grasslands, and finance lead intra-provincial collaborations. These findings offer new insights for integrating multi-level governance in ecological protection and ecological civilization construction.

Keywords: Intergovernmental relations; Ecological protection policy; Issuing entities; Social network analysis; The source region of the Yangtze River
Ecol. Civiliz.
2025,
2
(4), 10011; 
Open Access

Article

21 July 2025

Mechanism Obstacles and Path Breakthroughs for International Low-Carbon Technology Sharing

The deepening of global climate governance urgently needs to solve the institutional predicament between the monopoly and sharing of low-carbon technologies. In analyzing the institutional obstacles to the sharing of low-carbon technology, the study found significant asymmetric conflicts between developed and developing countries in technology supply, institutional rules, and market dynamics. The current international rule system (such as the Agreement on Trade-Related Aspects of Intellectual Property Rights and Bilateral Investment Agreement) has solidified the “central-periphery” pattern of technology distribution through tools such as “prohibition provisions on compliance requirements” and “green patent barriers”, resulting in developing countries facing dual pressures of “compliance costs” and “technology dependence”. In contrast, developed countries have fallen into the predicament of “innovation involution” due to the mismatch of technological application scenarios. Based on the theory of the technology life cycle and the perspective of subject complementarity, there is a structural mutual benefit space in the supply and demand of low-carbon technologies among different countries: developing countries can shorten the industrial decarbonization cycle through technology sharing, while developed countries rely on technology diffusion to digest excess capacity and consolidate their dominance in rules. By deconstructing the practical effectiveness of the low-carbon patent sharing platform and the defensive patent licensing model, it is highly feasible to reconstruct the technology sharing incentive framework with the “open-source mechanism”. Constructing a multi-level incentive mechanism to promote corporate participation, introducing dynamic defensive patent commitments, strengthening institutional capacity building, establishing a coordinated regulatory mechanism, and enhancing stakeholder compliance mechanisms are institutional optimization pathways. These provide a legal basis for harmonizing the exclusivity of intellectual property rights with the public nature of climate governance, and also offer strategic references for China’s participation in the formulation of global low-carbon technology regulations.

Keywords: Low-carbon technology; Technological monopoly; Technology sharing; Structural complementarity; Technology sharing platform
Clean Energy Sustain.
2025,
3
(3), 10009; 
Open Access

Article

21 July 2025

Dynamic Analysis of Shared Moorings in Different Wind Farm Layouts

The effects of shared mooring in offshore wind farms are investigated through numerical simulations in the present study. Different farm layouts are modelled and tested in SIMA coupled dynamic analysis software with three and four floaters. The wind turbine and the platform are based on the OC3 project from NREL: a 5-MW wind turbine and a spar floater with a 120-m draft. The water depth is 320 m, and the environmental loads are defined for an average operational condition. Firstly, the static results of the mooring line tension at the fairleads and anchors from the numerical model are compared with the values from the open-source MoorPy code. Then, domain simulations are conducted for three hours, and the dynamic behaviour of the floaters is analysed with a focus on surge and pitch motions. In addition, the dynamic stiffness effects of the polyester in the shared mooring line are considered in the SIMA simulations. The mooring line tensions are analysed, determining the global maximum tension across all systems. Results show that designs with two windward legs have significantly lower anchor mooring line tensions than those with a single windward leg, with no relevant variation in platform surge and pitch. Thus, the former systems are preferable for further investigation.

Keywords: Spar platform; Shared mooring; Offshore energy; Wind farm; Mooring dynamics
Open Access

Article

17 July 2025

Energy Drink Consumption among Adolescents between 13 and 18 Years in Lebanon: Prevalence, Patterns, and Predictors of Energy Drink Use and Dependence

Energy drinks (ED) use and addiction among adolescents is a growing concern, as they contain high levels of caffeine and other stimulants that can be addictive. This study aims to determine the prevalence of ED consumption among adolescents and assess the use and dependence predictors. A cross-sectional study was conducted over eight months, targeting 1855 adolescents from 12 schools during the 2022/2023 academic year. 55.5% of participants consumed EDs at least once last year. Around 15% reported being dependent on EDs, 34.7% reported mixing them with alcohol, and 25.3% said that they mixed them with caffeinated beverages. The odds of ED use were 3.63 among alcohol consumers, 2.67 times higher among waterpipe smokers, and 1.97 among those consuming them as sports drinks. These odds were 53% and 34% lower among females who knew their side effects, respectively. Among others, these. As regards dependence on EDs, those using them daily or weekly had 2.62 times higher odds of dependence than those using them less frequently. Students using EDs before physical activity had 2.33 times higher odds of dependence, in addition to those using them for self-confidence or to enhance their moral state. Spending more than 7 USD on EDs increased 1.72 times the odds of dependence. A high prevalence of ED use was found in this study, in addition to a high risk of dependence. Findings call for parents, educators, and healthcare providers to educate adolescents about the risks.

Keywords: Energy drink; Adolescent; Consumption; Dependence; Predictors
Lifespan Dev. Ment. Health
2025,
1
(3), 10011; 
Open Access

Review

16 July 2025

Heterogeneous Catalyzed Electrochemical Conversion of CO2 through C-N Bond Formation

The electrocatalytic transformation of carbon dioxide into valuable chemical compounds has gained increasing significance, particularly in the production of nitrogen-containing species via C-N bond formation. This review is organized around the “nitrogen source as the main thread, the product as the branch, and the mechanism as the underlying logic”, summarizing and discussing the latest research work on the formation of C-N bonds involving CO2 under electrochemical conditions. Firstly, these works are classified by the N-containing substrates (oxynitrides, dinitrogen gas, and ammonia) and productions (urea, amines, amides, carbamates, and amino acids). Then, various types of electrocatalysts are demonstrated in depth, including experimental and theoretical results. Finally, the conclusion is presented as well as the future perspectives.

Keywords: CO2 conversion; Nitrogen fixation; C-N bond formation; Electrosynthesis; Heterogeneous catalysis
Green Chem. Technol.
2025,
2
(3), 10009; 
Open Access

Article

15 July 2025

Exploring the Sustainable Path of Rural Governance: An Empirical Study on Digital Technology Empowering the “Fengqiao Experience” Model in the New Era

Understanding digital technology and digital inclusive finance in rural governance is key to exploring the sustainable development path of rural governance in China. This study constructs a multidimensional index evaluation system for the “Fengqiao Experience” rural governance model in the new era, measures the model’s rural governance level in 30 provinces in China (2011–2022), and empirically assesses digital technology’s impact on rural governance and its mechanism. The results are as follows: (1) During the sample survey period, the rural governance level of digital technology and “Fengqiao Experience” in 30 provinces in China has improved year by year. (2) Benchmark returns to reality and digital technology significantly promotes the improvement of rural governance levels, which remains valid after using GLS, replacing core explanatory variables, excluding the impact of the epidemic, and excluding municipalities directly under the central government. (3) Digital inclusive finance plays an intermediary role in the digital technology process, enabling rural governance. (4) Digital technology’s impact on rural governance has significant spatial spillover characteristics. Such technology helps improve the level of rural governance both locally and in surrounding areas. This study contributes to the understanding of the mechanism, effect, and regional differences of digital technology-enabled rural governance.

Keywords: Digital technology; Rural governance; Fengqiao Experience; Governance entities; Governance approaches
Rural Reg. Dev.
2025,
3
(4), 10012; 
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