Fused zirconia-mullite (ZM) and zirconia-alumina (ZA) are expensive aggregates used in refractory formulations to enhance thermal shock tolerance and corrosion resistance, respectively. A cost-effective alternative approach was explored in this work to produce 37.4 wt% ZrO2 containing ZM utilizing conventional reaction sintering of siliceous clay, calcined alumina and monoclinic ZrO2. A series of chemical reactions ensued from 1200 °C, forming low quartz and cristobalite from the clay, in situ ZrSiO4, monoclinic ZrO2, α-Al2O3 and traces of leucite. 1600 °C was required to fully form mullite and monoclinic ZrO2 but it had 26.5% porosity even after firing at 1650 °C for 2 h. It consisted of small equiaxed primary mullite grains secondary mullite rods, and scattered and clustered, round ZrO2 grains. With 1.05% CaO addition, tetragonal ZrO2 formed, but 22.7% porosity remained despite the presence of 13.5% liquid phase having a low viscosity (0.6 Pa.s, from FactSage). With 2.11% CaO, porosity reduced to 10.7% but mullite partly dissolved, forming α-Al2O3 (ZMA aggregate). The added CaO mostly remained in the intergranular glassy phase rather than inside the ZrO2 grains but increased the thickness of the secondary mullite and the ZrO2 grains. Mullite was completely lost with 4.21% CaO doping but favorably formed cubic ZrO2 containing up to 0.26 at% Ca, interlinked α-Al2O3 rods and attained a low porosity of 0.2%. This ZA aggregate is limited to 1550 °C application temperature as excess liquid phase drained out beyond that. 7.37% CaO addition was detrimental as it formed an excessive anorthite-like liquid phase that percolated out at 1550 °C with 5.6% weight loss. Thus, in ZM-based calcium aluminate cement bonded refractory castables, the final CaO content should be restricted to below 2.1% to avoid partial dissolution of mullite.
Although “climate litigation” is not an indigenous term in China, localizing it is essential to support the development of anindependent environmental legal knowledge system in China. Rooted in China’s judicial tradition, which emphasizes substantive rationality, traditional legal theories have primarily focused on environmental law. However, the contemporary practices in the rule of law have created an unclear trajectory for climate litigation. Research in this area has long been trapped in a paradigm that relies on lawsuits for ecological environmental damage compensation and environmental public interest litigation, leading to a significant disconnect between theoretical framworks and practical application. With the advancement of the "dual carbon" strategic goals—carbon peaking and carbon neutrality—it has become imperative to redefine the concept of climate litigation within the Chinese context. We need to establish a theoretical framework that aligns with the “dual carbon” objectives while providing theoretical and institutional support for climate litigation, ultimately contributing to the international discourse on climate justice. Additionally, Hong Kong’s proactive climate governance and robust ESG (Environmental, Social, and Governance) practices provide valuable insights for developing comprehensive climate litigation mechanisms. Based on this analysis, we propose concrete plans for building a climate litigation system in China, establishing a preventive relief system and a multi-source legal framework at the substantive level and developing climate judicial mechanisms for mitigation and adaptation at the procedural level.
Non-governmental environmental organizations are diverse in scope, goals and doctrine, ranging from natural history societies to green parties. It was from the 1960s that they became widespread worldwide. To characterize a French NGO and assess the changing trends in its objectives over time, we have qualitatively and quantitatively analyzed the journal it has published without interruption for 40 years: 140 issues, 4500 pages, and almost 250 keywords. The initial scope of the NGO was focused on ‘humans and nature’: we do not protect the environment against humans but with humans, i.e., at the same time as humans, which is the very definition of sustainable development, with its three-fold focus: nature, economy and social justice. The primary issues included recognizing water as a shared resource for all people, promoting sustainable agriculture and transportation (such as railways), advancing peace efforts, and protecting nature. This approach emphasizes a rigorous, evolving scientific perspective that goes beyond a focus on a few charismatic species (‘deluxe biodiversity’), embracing biodiversity in its entirety. Over time, the discourse has kept track of the shifting priorities of most Green parties: less and less focused on nature (e.g., forests, ecosystems) and more and more on social issues (e.g., health, housing, transport). However, it differs in not focusing on the idées fixes of the Greens (e.g., rejection of civil nuclear power, GMOs).
Intelligent factories provide flexible and adaptive production processes, offering significant competitive advantages to manufacturers and are widely studied in industrial production. Information technology is recognized as a key factor influencing the production efficiency and intelligence of Intelligent factories. However, current research has primarily focused on the operational processes of intelligent factories, with limited analysis of information technology. To address this gap, this paper conducts a bibliometric analysis of information technology in intelligent factories, along with a review of its development and applications. Firstly, the data collection and visualization methods of bibliometrics are introduced. Secondly, bibliometric analyses are performed using platforms such as VOSviewer and Scimago to investigate co-authorship, co-citation, and contributions from countries and institutions in the field of information technology for intelligent factories. Finally, a framework for information technology in intelligent factories is established, summarizing its development in terms of information acquisition, transmission, processing, management, and control. This paper aims to assist scholars in understanding the development trends of intelligent factory technology and enhancing the informatization level of intelligent factories.
Asthma is a common respiratory disorder characterized by chronic inflammation of the lower airways, contributing to significant morbidity, mortality, and a substantial global economic burden. It is now understood as a heterogeneous condition, with ongoing research shedding light on its complex immunological underpinnings. Ion channels, which are specialized transmembrane proteins that facilitate ion movement based on electrochemical gradients, play a crucial role in the pathophysiology of asthma. Ion channels regulate essential processes like maintaining epithelial hydroelectrolyte balance and also play a role in modulating immune responses involved in asthma. We discuss the connection between ion channel activity and immune regulation in asthma, focusing on ion channel regulation of immune cell behavior, airway hyperresponsiveness, and inflammation in asthma. Understanding ion channels in asthma could lead to the development of targeted therapies modulating their activity, thereby enhancing disease management and patient outcomes.
